Influence of Base Additive on Nanoporous Carbon Materials via HTC for Catalyst Support
Tripob Longprang1, Dolrudee Jaruwat2, Parncheewa Udomsap1,3, Nuwong Chollacoop3,
and Apiluck Eiad-ua1
1.College of Nanotechnology, King Mongkut's Institute of Technology Ladkrabang, Thailand.
2.Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Phayathai Rd., Phathumwan, Bangkok, 10330, Thailand.
3.National Metal and Materials Technology Center, National Science and Technology Development Agency, Pathumthani 12120, Thailand.
2.Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Phayathai Rd., Phathumwan, Bangkok, 10330, Thailand.
3.National Metal and Materials Technology Center, National Science and Technology Development Agency, Pathumthani 12120, Thailand.
Abstract: Nanoporous support materials were successfully synthesized from biomass via hydrothermal carbonization with base additives. This research study the effect of hydrothermal temperature (160-200 °C), hydrothermal time (4-24 h) and influence of base additive (NaOH, KOH, Na2CO3 and K2CO3) have been chosen in order to improve the surface structure. The samples have been characterized by scanning electron microscopy, nitrogen sorption, Fourier transform infrared spectroscopy and X-ray diffraction. The experimental results revealed that hydrothermal carbonization process and acid addition have effect on the properties of catalyst support. The results indicated that hydrothermal process at 200°C for 12 h and activation with KOH at 900°C for 2 h, exhibited the highest surface area, porosity and pore volume leading to increased distribution of metal on the carbon support.
Keywords: Biomass, Nanoporous carbon, Catalyst support, Hydrothermal carbonization.
Cite: Tripob Longprang, Dolrudee Jaruwat, Parncheewa Udomsap, Nuwong Chollacoop, Apiluck Eiad-ua, "Influence of Base Additive on Nanoporous Carbon Materials via HTC for Catalyst Support," International Journal of Materials Science and Engineering, Vol. 7, No. 2, pp. 34-39, June 2019. doi: 10.17706/ijmse.2019.7.2.34-39
Keywords: Biomass, Nanoporous carbon, Catalyst support, Hydrothermal carbonization.
Cite: Tripob Longprang, Dolrudee Jaruwat, Parncheewa Udomsap, Nuwong Chollacoop, Apiluck Eiad-ua, "Influence of Base Additive on Nanoporous Carbon Materials via HTC for Catalyst Support," International Journal of Materials Science and Engineering, Vol. 7, No. 2, pp. 34-39, June 2019. doi: 10.17706/ijmse.2019.7.2.34-39
General Information
ISSN: 2315-4527 (Print)
Abbreviated Title: Int. J. Mater. Sci. Eng.
Editor-in-Chief: Prof. Emeritus Dato' Dr. Muhammad Yahaya
DOI: 10.17706/ijmse
Abstracting/ Indexing: Ulrich's Periodicals Directory, Google Scholar, Crossref
E-mail: ijmse@iap.org
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